Deoxygenative Reduction of Organometallic Compounds by Hydrosilanes. An Organometallic Approach to Catalytic CO Hydrogenation.
نویسندگان
چکیده
منابع مشابه
Catalytic organometallic anticancer complexes.
Organometallic complexes offer chemistry that is not accessible to purely organic molecules and, hence, potentially new mechanisms of drug action. We show here that the presence of both an iodido ligand and a sigma-donor/pi-acceptor phenylazopyridine ligand confers remarkable inertness toward ligand substitution on the half-sandwich "piano-stool" ruthenium arene complexes [(eta(6)-arene)Ru(azpy...
متن کاملCruciaromaticity in organometallic compounds
A recent suggestion, that transition metal complexes of unsaturated ligands can be regarded as cruciconjugated, is explored by studies of various complexes of Fe(II), the aromaticity of the resulting i systems being analyzed in terms of PMO theory. This approach is also applied to porphyrin. The conclusions are supported by preliminary SCF and MNDO calculations.
متن کاملOrganometallic Anticancer Compounds
Gilles Gasser,* Ingo Ott,* and Nils Metzler-Nolte* Institute of Inorganic Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057 Zurich, Switzerland, Institute of Pharmaceutical Chemistry, Technische Universit€ at Braunschweig, Beethovenstrasse 55, 38106 Braunschweig, Germany, and Chair of Inorganic Chemistry I, Bioinorganic Chemistry, Faculty of Chemistry and Biochemistry, Ruhr Univ...
متن کاملTherapeutic Organometallic Compounds
Most drugs used today are purely organic compounds. Especially after the enormous success of the cisplatin (Fig 1) in tumor treatment, interest in metal complexes has grown (Allardyce & Dyson, 2006). Synthetic organometallic compounds are generally considered to be toxic or non-compatible with biological systems. Despite this perception, the medicinal properties of organometallic compounds, in ...
متن کاملCopolymerization of Vinyl Chloride by Organometallic Compounds
ABSTRACT The copolymerizations of vinyl chloride with o-olefin or acrylic compounds were investigated with organometallic compounds as catalysts. In general, organoaluminium compounds need to be treated with a complexing agent such as tetrahydrofuran prior to use. Otherwise the former reacts with polyvinyl chloride and loses its activity. The copolymer of vinyl chloride and propylene was thus o...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1998
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1998.783